Effect of the chemical additives on the quality of extra heavy crude extracted with propane
Keywords:
Chemical additives, Extra heavy crude, crude quality, reservoir, asphaltenes, resinAbstract
The purpose of this study is to evaluate the effect of chemical additives on the quality of Hamaca extra heavy crude using propane as solvent of extraction in the reservoir conditions (60 ºC and 110 psi). It begins with an evaluation in a SFE□ISCO extraction system with propane. Different additives were used, among them: toluene, toluene/isopropanol, dodecylbenzene sulfonic acid(DDBSA), 1-octadecene maleic anhydride (ODMA) and maleic anhydride (MA). Consecutive by an analysis of saturated, aromatics, resin and asphaltenes (SARA) with the chromatography technique in fine layer connected to a flame ionization detector (TLC-DFID).In the end, One can conclude that the asphaltenes content is reduced in 60% with only propane. But, using additives the deasphalting is 30% aproximately. In other words, only the propane is better at deasphalting than aditively propane.
References
Deo, M. D., Hwang, J. And Hanson, F. V. “Dynamic behaviour of supercritical fluid extractions of crude oil and its vacuum residue”, FUEL Vol. 75, Nº 13, pp. 1591 – 1595, 1996.
Hwang, R.J. And Ortiz, J. “Mitigation of asphaltics deposition during CO2 flood by enhancing CO2 solvency with chemical modifiers”, Organic Geochemistry, Vol. 31, pp. 1451 – 1462, 2000.
Monin, J.C., Barth, D., Perrut, M. Y Durand, B. “Extraction of hidrocarbons from sedimentary rocks by supercritical carbon dioxide”, Org. Geochem. 13, 4-6, 1079-1086, 1987.
Pillon, L. “Effect of dispersants and floculants on the colloidal stability of asphaltenes”. Petroleum Science and Technology, pp. 863-873, Canada, 2001.
Ramirez, D., Ovalles, C., “Efecto de la presencia de aditivos químicos en la extracción de crudos extrapesados con propano”, Revista Electrónica Facultad de Ingeniería UVM, Vol 3, Número 1 Enr/Jun, Año, 2009.
Rengel, P. “Efecto de iniciadores de radicales libres en reacciones de mejoramiento de crudos a baja severidad”, Tesis de Grado para optar al título de Licenciado en Química ante la Universidad Simón Bolívar, Julio 2002.
Rose, J. L., Svrcek, W. Y., Monnery, W. D. And Chong, K. “Fractionation of Peace River Bitumen using supercritical ethane and carbón dioxide”, Ind. Eng. Chem. Res., Vol. 39, Nº 10, pp. 3875 – 3883, 2000.
Sol, B., Romero, E., Carbognani, L., Sanchez, V. And Sucre, L. “An alternative technique for hydrocarbon class-type (SARA) separation”. Revista Técnica Intevep, Vol. 5, pp. 39-43, Enero 1985.
Subramanian, M., Deo, M.D. Y Hanson F. V. “Supercritical fluid extraction of UINTA basin bitumens”. University of Utah, Department of Chemical and Fuels Engineering, Vol. 2, pp. 193-204,1995.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2012 Deysi Ramírez , C Ovalles

This work is licensed under a Creative Commons Attribution 4.0 International License.